冀晓敏,焦利勇,柳雅军,李琳琳,马倩云.水性UV固化涂料用多羟甲基苯酚丙烯酸酯的合成[J].包装工程,2012,33(9):62-65,69.
JI Xiao-min,JIAO Li-yong,LIU Ya-jun,LI Lin-lin,MA Qian-yun.Synthesis of Multi-hydroxymethyl-phenol Acrylate for Waterborne UV Curing Coating[J].Packaging Engineering,2012,33(9):62-65,69. |
| 水性UV固化涂料用多羟甲基苯酚丙烯酸酯的合成 |
| Synthesis of Multi-hydroxymethyl-phenol Acrylate for Waterborne UV Curing Coating |
| 投稿时间：2012-02-01 修订日期：2012-05-10 |
| DOI： |
| 中文关键词: 多羟甲基苯酚丙烯酸酯 水性 UV固化 涂料 |
| 英文关键词: multi-hydroxymethyl-phenol acrylate waterborne UV curing coating |
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| 中文摘要: |
| 以多羟甲基苯酚钠和丙烯酰氯为原料，合成了适用于水性UV固化涂料的多羟甲基苯酚丙烯酸酯，通过红外光谱表征了产物的化学结构。探讨了物料比、反应温度、反应时间和催化剂用量等因素对产物产率的影响，结果表明：当n(多羟甲基苯酚钠)∶n(丙烯酰氯)=1∶2、反应温度为0~-5 ℃、反应时间为2.5 h、催化剂四丁基溴化铵用量为0.04%（占物料质量比）时，最有利于产物的合成；多羟甲基苯酚丙烯酸酯的水溶性及涂膜性能，也能较好地满足水性UV固化涂料的应用。 |
| 英文摘要: |
| Multi-hydroxymethyl-phenol acrylate which is suitable for waterborne UV curing coating was synthesized by using multi-hydroxymethyl phenol sodium and acryloyl chloride as raw material. Chemical structure of the product was characterized by FT-IR. The relation between the production yield and material ratio, reaction temperature, reaction time and catalyst content was discussed. The results showed that the most favorable reaction condition is when n(multihydroxymethyl phenol sodium)∶n(acryloyl chloride)=1∶2, reaction temperature at 0~- 5℃, reaction time 2.5 h, the content of tetrabutyl ammonium bromide 0.04%(accounting for materials quality ratio); water-soluble and film properties of the multi-hydroxymethyl-phenol acrylate can satisfy the application of waterborne UV curing coating. |
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