朱翔,汪宣,徐继俊,徐文君,沈建敏,蓝闽波,赵红莉.三维多孔碳纳米材料用于烟用纸张中五氯苯酚的测定方法研究[J].包装工程,2023,44(3):224-232.
ZHU Xiang,WANG Xuan,XU Ji-jun,XU Wen-jun,SHEN Jian-min,LAN Min-bo,ZHAO Hong-li.Determination of Pentachlorophenol in Cigarette Paper Using Three-dimensional Porous Carbon Nanomaterials[J].Packaging Engineering,2023,44(3):224-232. |
| 三维多孔碳纳米材料用于烟用纸张中五氯苯酚的测定方法研究 |
| Determination of Pentachlorophenol in Cigarette Paper Using Three-dimensional Porous Carbon Nanomaterials |
| |
| DOI：10.19554/j.cnki.1001-3563.2023.03.028 |
| 中文关键词: 烟用纸张 三维多孔碳纳米材料 电化学传感器 五氯苯酚 检测/监测 |
| 英文关键词: cigarette paper three-dimensional porous carbon nanomaterials electrochemical sensor, pentachlorophenol determination/monitoring |
| 基金项目:上海烟草集团有限责任公司科技项目(K2017–001);上海烟草包装印刷有限公司科技项目(K2021–006) |
|
| 摘要点击次数: |
| 全文下载次数: |
| 中文摘要: |
| 目的 建立烟用纸张中五氯苯酚(PCP)的快速电化学测定方法。方法 基于沸石咪唑酯骨架(ZIF)的ZIF–8、ZIF–67具有相同的晶胞参数和同构性，以ZIF–8@ZIF–67为模板制备三维纳米多孔碳(NGPC)。利用NGPC的高比表面积以及优异的电子传递效率构建的传感器(记作NGPC/SPCE)对PCP具有很好的响应。结果 在0.86 V的检测电位下，NGPC/SPCE具有较高的灵敏度(2.452 µA.cm−2.L.mg−1)。传感器对PCP的检测具有良好的选择性。传感器对PCP检测具有较好的准确度和精密度。3个浓度梯度的回收率为95.7~98.6;6次测试结果的相对标准偏差为2.07%。传感器对PCP的检测具有较好的长期稳定性。同一传感器连续检测25 d后，仍保持原先88.1%的响应。结论 文中构建的传感器适用于对烟用纸张中PCP的检测，并能获得理想的检测结果。 |
| 英文摘要: |
| The work aims to develop a rapid electrochemical determination method of pentachlorophenol (PCP) in cigarette paper. Based on the same unit cell parameters and isomorphism of ZIF-8 and ZIF-67, the three-dimensional nanoporous carbon (NGPC) was prepared with ZIF-8@ZIF-67 as a template. Considering the advantage of the large specific surface area and high electron transfer efficiency of NGPC, the constructed sensor (named NGPC/SPCE) had a good response to PCP. At the detection potential of 0.86 V, the sensor had a high sensitivity (2.452 µA.cm−2.L.mg−1) with good selectivity. Besides, the sensor possessed good accuracy and precision for detection of PCP. The recovery results of the three concentration gradients were between 95.7%-98.6%. Additionally, the relative standard deviation of the six consecutive test results was 2.07%. The sensor had good long-term stability for detection of PCP. After 25 days of continuous detection, the sensor can still maintain 88.1% of the initial sensitivity. Thus, the sensor developed in the work is suitable for detection of PCP in cigarette paper with a satisfactory result. |
|
查看全文
查看/发表评论 下载PDF阅读器 |
| 关闭 |
渝公网安备 50010702501716号